Critical Thinking Questions 1. Draw the structure for the product from the reaction of 1,3-cyclohexadiene and maleic acid (cis-2-butenedioic acid). 2. What is the product expected from the reaction of 1,3-butadiene and 3-sulfolene? Why is this not a major concern as a by-product? Part B, the dimer dicyclopentadiene is a possible contaminant of cyclopentadi- ene. It is also a diene. Can dicyclopentadiene undergo reaction with cyclopentadi- ene? Can dicyclopentadiene act as a diene and undergo reaction with the anhydride 3. In ? Show structures for any possible products from these reactions. 4. 5. Explain why reverse Diels-Alder reactions are possible at high temperatures. Predict the Diels-Alder product of each of the following reactions: heat CO2CH3 heat CO2CH3 CN heat 6. 7. Explain the principal synthetic value of the Diels-Alder reaction Explain why the compound shown here fails to react as a Diels-Alder diene.
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